Filter List

CRC 1078/1: Structural Basis of Proton Release in Water Oxidation by Photosystem II (SP A05)

Zouni, Athina, (Experimental Biophysics)

Duration of project: 01/2013 - 03/2021

In oxygenic photosynthesis, water is oxidized and dioxygen is formed at the Mn4Ca complex of photosystem II (PSII), a 750 kDa protein-cofactor complex embedded in the thylakoid membrane of plants and cyanobacteria. Reliable structural models of PSII ...

CRC 1109/1: Distorted Metal Oxides by Fluoride Doping and/or Mechanochemical Activation (SP C01)

Kemnitz, Erhard, Prof. Dr. sc. nat. (Inorganic and General Chemistry III)

Duration of project: 04/2014 - 12/2017

Mittels fluorolytischer Sol-Gel- und mechanochemischer Synthese sollen kontrolliert strukturelle Störungen in Metalloxidphasen und deren Präkursoren eingebracht werden. Das beinhaltet sowohl die Synthese neuer kristalliner Modellverbindungen mit nied ...

CRC 1109/1: Oxo Frameworks in Molecular Compounds: Early Stage Modelling, Tailored Structural Motifs for Novel Materials and Water Reactivity (SP A04)

Limberg, Christian, Prof. Dr. (Inorganic and General Chemistry I)

Duration of project: 04/2014 - 12/2017

This project will deal with well-defined molecular metal oxo compounds, which are synthesised/trapped to investigate their properties, their (water) reactivity and their dissolution/degradation behaviour. On the one hand we anticipate to thereby gath ...

CRC 1109/1: Siloxanes, Alumoxanes and Alumosiloxanes As Models for Surface Defects in Hydrolysis and Condensation Reactions (SP A01)

Braun, Thomas, Prof. Dr. (Inorganic Chemistry)

Duration of project: 04/2014 - 12/2017

Subject of the project is to study hydrolysis and condensation processes at strained siloxane, alumoxane and alumosiloxane compounds. The latter can be considered to be model com-pounds for defect structures at silicate or aluminosilicate surfaces. T ...

CRC 1109/1: Understanding of Metal Oxide/Water Systems at the Molecular Scale. Structural Evolution, Interfaces, and Dissolutions

Limberg, Christian, Prof. Dr. (Inorganic and General Chemistry I)

Duration of project: 04/2014 - 12/2017

The Collaborative Research Centre 1109 is an interdisciplinary research platform bringing together scientists from four universities and three non-university institutions. It comprises 18 research projects led by 23 principal investigators (PIs) with ...

CRC 1349/1: Controlling Fluorination Reactions by Hydrogen-Bridges in the Coordination Sphere of Au and Pt Complexes (SP A01)

Braun, Thomas, Prof. Dr. (Inorganic Chemistry)

Duration of project: 01/2019 - 12/2022

In the subproject A1|Braun, hydrogen bonds in the coordination sphere of gold and platinum complexes will be used to develop hydrofluorination or difluorination reactions with HF sources or XeF2, respectively. The Fluorospecific Interactions will all ...

CRC 1349/1: Cooperating Lewis Pairs Based on Fluorinated Bismuth and Aluminium Acceptor Moieties (SP B01)

Limberg, Christian, Prof. Dr. (Inorganic and General Chemistry I)

Duration of project: 01/2019 - 12/2022

Fluoride and fluorinated organic and inorganic residues will be utilized to create Lewis-acidic bis-muth and aluminium centres linked via organic spacer units (xanthene/dibenzofurane) to phos-phane or electron-rich transition metal moieties. These co ...

CRC 1349/1: Fluorinated Aluminum Compounds as Lewis-Acids for the Activation of Small Molecules (SP B04)

Braun, Thomas, Prof. Dr. (Inorganic Chemistry)

Duration of project: 01/2019 - 12/2022

In the subproject B4|Braun/Riedel small molecules such as HSiEt3, HGeEt3 or H2, and FSiEt3, FGeEt3, HF or F2 will be activated at the nanoscopic aluminum chloro fluoride ACF (AlClxF3-x, x = 0,05-0,30) as well as at molecular aluminum pentafluoroortho ...

CRC 1349/1: Indigo Switch for the Quantification of Fluorine-Specific Interactions (SP C01)

Hecht, Stefan, Prof. (Organic Chemistry and Functional Materials)

Duration of project: 01/2019 - 12/2022

In this project indigo derivatives with (partially) fluorinated residues will be synthesized and the equilibrium (ratio of E and Z isomers) as well as the thermal half-life of the photogenerated meta-stable Z isomer will be measured under various con ...

CRC 765/3: Spacer Structure (SP A03)

Hecht, Stefan, Prof. (Organic Chemistry and Functional Materials)

Duration of project: 01/2008 - 12/2019

In this project functional host-guest systems will developed by exploiting multivalent and cooperative effects in combination with photoswitchable non-covalent interactions. Thus light will be used to externally control the supramolecular polymerizat ...