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CRC 1109/1: Distorted Metal Oxides by Fluoride Doping and/or Mechanochemical Activation (SP C01)

Kemnitz, Erhard, Prof. Dr. sc. nat. (Inorganic and General Chemistry III)

Duration of Project: 04/2014 - 12/2017

Mittels fluorolytischer Sol-Gel- und mechanochemischer Synthese sollen kontrolliert strukturelle Störungen in Metalloxidphasen und deren Präkursoren eingebracht werden. Das beinhaltet sowohl die Synthese neuer kristalliner Modellverbindungen mit nied ...

CRC 1109/1: Oxo Frameworks in Molecular Compounds: Early Stage Modelling, Tailored Structural Motifs for Novel Materials and Water Reactivity (SP A04)

Limberg, Christian, Prof. Dr. (Inorganic and General Chemistry I)

Duration of Project: 04/2014 - 12/2017

This project will deal with well-defined molecular metal oxo compounds, which are synthesised/trapped to investigate their properties, their (water) reactivity and their dissolution/degradation behaviour. On the one hand we anticipate to thereby gath ...

CRC 1109/1: Siloxanes, Alumoxanes and Alumosiloxanes As Models for Surface Defects in Hydrolysis and Condensation Reactions (SP A01)

Braun, Thomas, Prof. Dr. (Inorganic Chemistry)

Duration of Project: 04/2014 - 12/2017

Subject of the project is to study hydrolysis and condensation processes at strained siloxane, alumoxane and alumosiloxane compounds. The latter can be considered to be model com-pounds for defect structures at silicate or aluminosilicate surfaces. T ...

CRC 1349/1: Controlling Fluorination Reactions by Hydrogen-Bridges in the Coordination Sphere of Au and Pt Complexes (SP A01)

Braun, Thomas, Prof. Dr. (Inorganic Chemistry)

Duration of Project: 01/2019 - 12/2022

In the subproject A1|Braun, hydrogen bonds in the coordination sphere of gold and platinum complexes will be used to develop hydrofluorination or difluorination reactions with HF sources or XeF2, respectively. The Fluorospecific Interactions will all ...

CRC 1349/1: Cooperating Lewis Pairs Based on Fluorinated Bismuth and Aluminium Acceptor Moieties (SP B01)

Limberg, Christian, Prof. Dr. (Inorganic and General Chemistry I)

Duration of Project: 01/2019 - 12/2022

Fluoride and fluorinated organic and inorganic residues will be utilized to create Lewis-acidic bis-muth and aluminium centres linked via organic spacer units (xanthene/dibenzofurane) to phos-phane or electron-rich transition metal moieties. These co ...

CRC 1349/1: Fluorinated Aluminum Compounds as Lewis-Acids for the Activation of Small Molecules (SP B04)

Braun, Thomas, Prof. Dr. (Inorganic Chemistry)

Duration of Project: 01/2019 - 12/2022

In the subproject B4|Braun/Riedel small molecules such as HSiEt3, HGeEt3 or H2, and FSiEt3, FGeEt3, HF or F2 will be activated at the nanoscopic aluminum chloro fluoride ACF (AlClxF3-x, x = 0,05-0,30) as well as at molecular aluminum pentafluoroortho ...

SPP 2102: The Photocatalytic Reduction of CO2 with Heterodinuclear Catalysts Based on Earth Abundant Metals

Schwalbe, Matthias, (Inorganic and General Chemistry I)

Duration of Project: 01/2019 - 12/2022

Our goal is the development and in detail investigation of catalytic systems for the light-driven reduction of carbon dioxide. A major aim is to compare inter- and intramolecular systems that are based on the same combination of photosensitizer and c ...