CRC 1349/1: Controlling Fluorination Reactions by Hydrogen-Bridges in the Coordination Sphere of Au and Pt Complexes (SP A01)


In the subproject A1|Braun, hydrogen bonds in the coordination sphere of gold and platinum complexes will be used to develop hydrofluorination or difluorination reactions with HF sources or XeF2, respectively. The Fluorospecific Interactions will allow controlling the selectivity of the transformations. In model reactions, key-steps of putative catalytic cycles will be studied.


Principal Investigators
Braun, Thomas Prof. Dr. (Details) (Inorganic Chemistry)

Participating external organizations

Duration of Project
Start date: 01/2019
End date: 12/2022

Research Areas
Anorganische Chemie

Publications
Ò. Torres, N. Pfister, T. Braun, P. Wittwer, Dalton Trans. 2019, 48, 6153-6161.
"C–F activation of perfluorophenazine at nickel: selectivity and mechanistic investigations"

M. Talavera, R. Müller, T. Ahrens, C. N. von Hahmann, B. Braun-Cula, M. Kaupp, T. Braun, Faraday Discuss. 2019, 220, 328-349.
"Activation of tetrafluoropropenes by rhodium(I) germyl and silyl complexes"

Last updated on 2021-08-04 at 11:32